Sign up through this link, and choose Payoneer as your payment method. Then, click on the registration button and complete the 4 registration steps.
Make sure that you have your local bank account details handy as you'll need them during the sign up.
Step 1: Enter your details
Step 2: Enter your address and phone number
Step 3: Create a password and set your security question
Step 4: Enter your local bank account details
Once you have submitted your Payoneer application, you can view your account status at any time by logging in to your Payoneer Account - My Account.
New applications are usually reviewed immediately. Once approved, you will receive an email confirmation with further details. In some situations, you may be asked to provide extra details such as a copy of your ID, Certificate of Incorporation, bank statement or other documents.